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What law states that energy can be converted from one form to another,but cannot be created or destroyed?


A) universal law
B) first law of thermodynamics
C) law of mass conservation
D) law of conservation of energy
E) law of constant energy

F) D) and E)
G) A) and B)

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When 0.7521 g of benzoic acid was burned in a calorimeter containing 1000.g of water,a temperature rise of 3.60°C was observed.What is the heat capacity of the bomb calorimeter,excluding the water? The heat of combustion of benzoic acid is -26.42 kJ/g.


A) 15.9 kJ/°C
B) 4.2 kJ/°C
C) 5.5 kJ/°C
D) 1.3 kJ/°C
E) 752 kJ/°C

F) A) and D)
G) C) and D)

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A system absorbs 21.6 kJ of heat while performing 6.9 kJ of work on the surroundings.If the initial internal energy,U,is 61.2 kJ,what is the final value of U?


A) 32.7 kJ
B) 46.5 kJ
C) 61.2 kJ
D) 75.9 kJ
E) 89.7 kJ

F) B) and C)
G) D) and E)

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Your favorite candy bar,Gummy Beakers,contains 1.2 × 106 J of energy while your favorite soft drink,Bolt,contains 6.7 × 105 J.If you eat two packs of Gummy Beakers a day and drink 3 cans of Bolt,what percent of your 2000 Calorie daily food intake is left for broccoli,beans,beef,etc.? (1 cal = 4.184 J)


A) 53%
B) 47%
C) 27%
D) 11%
E) 0%

F) C) and D)
G) C) and E)

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Chemical reactions in a bomb calorimeter occur at constant pressure.

A) True
B) False

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Which is not a state function?


A) internal energy
B) volume
C) work
D) pressure
E) enthalpy

F) B) and E)
G) All of the above

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For which of the substances below is ΔHof = 0?


A) O2(g)
B) N2(l)
C) Na(g)
D) Xe(l)
E) A and B

F) D) and E)
G) A) and D)

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What is ΔH°rxn for the following reaction? SiO2(s) + 4HCl(g) → SiCl4(g) + 2H2O(g) Substance ΔH°f(kJ/mol) SiO2(s) -859.3 SiCl4(g) -662.8 HCl(g) -92.3 H2O(g) -241.8


A) -1856.2 kJ/mol
B) -1372.6 kJ/mol
C) -47.0 kJ/mol
D) 82.1 kJ/mol
E) 530.6 kJ/mol

F) None of the above
G) B) and E)

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If two solutions are mixed together in a container and the container "feels hot",then


A) the reaction is endothermic.
B) the reaction is exothermic.
C) the energy of the universe is increased.
D) the energy of both the system and the surroundings is decreased.
E) the energy of the system is increased.

F) All of the above
G) A) and B)

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A glass containing 200.0 g of H2O at 20.0°C was placed in a refrigerator.The water loses 11.7 kJ as it cools to a constant temperature.What is its new temperature? The specific heat of water is 4.184 J/g·°C.


A) 0.0°C
B) 4.0°C
C) 6.0°C
D) 14.0°C
E) 34.0°C

F) A) and B)
G) None of the above

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Two solutions (the system) ,each with a volume of 25.0 mL at 25.0°C,are mixed in a beaker.A reaction occurs between them,and the temperature rises to 35.0°C.After the products have equilibrated with the surroundings,the temperature is again 25.0°C and the total volume is 50.0 mL.No gases are involved in the reaction.Which relationship concerning the change from initial to final states (both at 25.0°C) is correct?


A) ΔU = 0
B) ΔH = 0
C) ΔU > 0
D) q = 0
E) W = 0

F) B) and D)
G) B) and E)

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Consider the following two representations of chemical reactions.Each sphere represents 1 mol of atoms. Consider the following two representations of chemical reactions.Each sphere represents 1 mol of atoms.   What is ΔHº<sub>rxn</sub> for the following reaction? CS(g) + O(g) → CO(g) + S(g)  A) -359 kJ/mol B) 1434 kJ/mol C) -7142 kJ/mol D) -1434 kJ/mol E) 7142 kJ/mol What is ΔHºrxn for the following reaction? CS(g) + O(g) → CO(g) + S(g)


A) -359 kJ/mol
B) 1434 kJ/mol
C) -7142 kJ/mol
D) -1434 kJ/mol
E) 7142 kJ/mol

F) A) and B)
G) B) and D)

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For which reaction is ΔH approximately (or exactly) equal to ΔU?


A) H2(g) + Br2(g) → 2HBr(g)
B) H2O(l) → H2O(g)
C) CaCO3(s) → CaO(s) + CO2(g)
D) 2H(g) + O(g) → H2O(l)
E) CH4(g) + 2O2(g) → CO2(g) + 2H2O(l)

F) C) and E)
G) A) and D)

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An endothermic reaction causes the surroundings to


A) warm up.
B) become acidic.
C) condense.
D) decrease in temperature.
E) release CO2.

F) A) and E)
G) A) and D)

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The dissolution of barium hydroxide in water is an exothermic process.Which statement is correct?


A) The enthalpy of solid barium hydroxide plus pure water is less than that of the solution,at the same temperature.
B) The enthalpy of solid barium hydroxide plus pure water is greater than that of the solution,at the same temperature.
C) The enthalpy of solid barium hydroxide plus pure water is the same as that of the solution,at the same temperature.
D) The temperature of the solution is lower than of the barium hydroxide and water before mixing.
E) When barium hydroxide dissolves in water,the system does work on the surroundings.

F) A) and B)
G) B) and D)

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The combustion of pentane produces heat according to the following thermochemical equation. C5H12(l) + 8O2(g) → 5CO2(g) + 6H2O(l) ΔH°rxn = -3510 kJ/mol How many grams of CO2 is produced per 2.50 × 103 kJ of heat released?


A) 6.27 g
B) 31.3 g
C) 61.8 g
D) 157 g
E) 220 g

F) C) and E)
G) B) and E)

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A system delivers 1275 J of heat while the surroundings perform 854 J of work on it.What is ΔU of the system?


A) -2129 J
B) -421 J
C) +421 J
D) +2129 J
E) -1275 J

F) A) and B)
G) A) and C)

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A student used a bomb calorimeter to determine the heat of combustion of an unknown compound.If the student ignored the heat capacity of the bomb calorimeter,the heat capacity of the unknown compound would be _________ the accepted value.


A) greater than (i.e.,less negative)
B) less than (i.e.,more negative)
C) equal to

D) All of the above
E) A) and B)

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How much heat is released if 7.15 g CaO(s) is added to 152 g of H2O(l) ? CaO(s) + H2O(l) → Ca(OH) 2(s) ΔH°rxn = -64.8 kJ/mol


A) 7.68 kJ
B) 8.26 kJ
C) 508 kJ
D) 547 kJ
E) 555 kJ

F) C) and D)
G) A) and B)

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What is ΔH°rxn for the following reaction? NO2(g) + CO(g) → CO2(g) + NO(g) Substance ΔH°f(kJ/mol) NO(g) +90.4 NO2(g) +33.85 CO(g) -110.5 CO2(g) -393.5


A) 339.6 kJ
B) 379.8 kJ
C) -226.5 kJ
D) -339.6 kJ
E) -379.8 kJ

F) A) and B)
G) A) and C)

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