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Ethylene glycol,used as a coolant in automotive engines,has a specific heat capacity of 2.42 J/g°C.Calculate q when 3.65 kg of ethylene glycol is cooled from 132°C to 85°C.


A) -1900 kJ
B) -420 kJ
C) -99 kJ
D) -0.42 kJ
E) -4.2 × 10-6 kJ

F) All of the above
G) B) and C)

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The sign of q when heat is absorbed by the system is ___________.

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In an endothermic reaction,in going from the reactants to the products at the same temperature,the value of q is negative.

A) True
B) False

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Cold packs,whose temperatures are lowered when ammonium nitrate dissolves in water,are carried by athletic trainers when transporting ice is not possible.Which of the following is true of this reaction?


A) ΔH< 0,process is exothermic
B) ΔH> 0,process is exothermic
C) ΔH< 0,process is endothermic
D) ΔH> 0,process is endothermic
E) ΔH = 0,since cold packs are sealed

F) A) and E)
G) A) and B)

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An exothermic reaction causes the surroundings to


A) warm up.
B) become acidic.
C) expand.
D) decrease its temperature.
E) release CO2.

F) A) and C)
G) A) and D)

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Solid sodium peroxide (Na2O2) reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas.How much heat is released if 327.2 g of oxygen gas is produced from the reaction of sodium peroxide and water under standard-state conditions? Substance ΔH°f(kJ/mol) Na2O2 (s) -510.9 NaOH(aq) -469.6 H2O(l) -285.8


A) 46,630 kJ
B) 1457 kJ
C) 6689 kJ
D) 3345 kJ
E) 2914 kJ

F) A) and D)
G) C) and D)

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What is ΔH°rxn for the reaction 2Al2O3(s) → 4Al(s) + 3O2(g) ? ΔH°f(Al2O3(s) ) = -1670 kJ/mol


A) 3340 kJ/mol
B) 1670 kJ/mol
C) -3340 kJ/mol
D) -1670 kJ/mol
E) -835 kJ/mol

F) B) and E)
G) A) and B)

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Which relationship is always correct?


A) potential energy + kinetic energy = constant
B) Δ = q + W
C) ΔU = ΔH - PΔV
D) H = U + PV
E) ΔH = q V

F) None of the above
G) A) and B)

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A system that does no work but which receives heat from the surroundings has


A) q < 0,ΔU > 0.
B) q > 0,ΔU < 0.
C) q = ΔU.
D) q = -ΔU.
E) w = ΔU.

F) A) and B)
G) A) and C)

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The work done on the surroundings by the expansion of a gas is w = -PΔV.

A) True
B) False

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Using Hess's law,what is ΔH°rxn for the following reaction? WO3(s) + 3H2(g) → W(s) + 3H2O(g) 2W(s) + 3O2(g) →2WO3(s) ΔH°rxn = -1685.8 kJ/mol 2H2(g) + O2(g) → 2H2O(g) ΔH°rxn = -483.6 kJ/mol


A) 117.5 kJ/mol
B) 235.0 kJ/mol
C) 359.3 kJ/mol
D) 1202.2 kJ/mol
E) 2169.4 kJ/mol

F) A) and C)
G) D) and E)

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What is ΔH°rxn for the following reaction? C6H6(l) + 15/2 O2(g) → 6CO2(g) + 3H2O(l) 6C(graphite) + 3H2(g) → C6H6(l) ΔH°rxn = +49.0 kJ/mol C(graphite) + O2(g) → CO2(g) ΔH°rxn = -393.5 kJ/mol H2(g) + ½O2(g) → H2O(l) ΔH°rxn = -285.8 kJ/mol


A) -630.3 kJ/mol
B) -2597.8 kJ/mol
C) -3169.4kJ/mol
D) -3267.4 kJ/mol
E) 630.3 kJ/mol

F) D) and E)
G) B) and D)

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Which equation has a ΔHrxn that is not equal to ΔHof of the product? rev: 04_28_2015_QC_CS-14747


A) F2(g) + ½O2(g) → F2O(g)
B) O2(g) + 2H2(g) → 2 H2O(g)
C) H2(g) + ½O2(g) + → H2O(l)
D) Ti(s) + 2Cl2(g) → TiCl4(l)
E) ½H2(g) + ½ Cl2(g) → HCl(g)

F) A) and B)
G) B) and E)

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Sand is converted to pure silicon in a three-step process.The final step in this process is as follows. SiCl4(g) + 2Mg(s) → 2MgCl(s) + Si(s) ΔH°rxn = -625.6 kJ/mol What is the enthalpy change if 25.0 mol of silicon tetrachloride is converted to elemental silicon?


A) -25.0 kJ
B) -626 kJ
C) -1.56 × l04 kJ
D) -3.13 × 104 kJ
E) -3.13 × 103 kJ

F) B) and D)
G) A) and E)

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A(n)___________ __________ is a process where heat is released to the surroundings.

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Which of the following processes always results in an increase in the energy of a system?


A) The system loses heat and does work on the surroundings.
B) The system gains heat and does work on the surroundings.
C) The system loses heat and has work done on it by the surroundings.
D) The system gains heat and has work done on it by the surroundings.
E) None of these is always true.

F) A) and E)
G) D) and E)

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The highly exothermic thermite reaction,in which aluminum reduces iron(III) oxide to elemental iron,has been used by railroad repair crews to weld rails together. 2Al(s) + Fe2O3(s) → 2Fe(s) + Al2O3(s) ΔH°rxn = -847.6 kJ/mol What mass of iron is formed if 725 kJ of heat are released?


A) 23.9 g
B) 47.8 g
C) 65.3 g
D) 95.5 g
E) 112 g

F) A) and B)
G) A) and C)

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A system initially has an internal energy U of 504 J.It undergoes a process during which it releases 111 J of heat energy to the surroundings,and does work of 222 J.What is the final energy of the system,in J?


A) 171 J
B) 393 J
C) 504 J
D) 615 J
E) 837 J

F) A) and D)
G) A) and E)

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Glycine,C2H5O2N,is important for biological energy.The combustion reaction of glycine is described by the following thermochemical equation. 4C2H5O2N(s) + 9O2(g) → 8CO2(g) + 10H2O(l) + 2N2(g) ΔH°rxn = -3896 kJ/mol What is the standard enthalpy of formation of solid glycine?


A) -51.90 kJ/mol
B) -527.5 kJ/mol
C) -974.0 kJ/mol
D) -1502 kJ/mol
E) -2476 kJ/mol

F) B) and C)
G) B) and E)

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If,as a pioneer,you wished to warm your room by taking an object heated on top of a pot-bellied stove to it,which of the following 15-pound objects,each heated to 100°C,would be the best choice? The specific heat capacity (in J/g·°C) for each substance is given in parentheses.Iron (0.450) ,copper (0.387) ,granite (0.79) ,gold (0.129) ,water (4.184) .


A) iron
B) copper
C) granite
D) gold
E) H2O

F) A) and E)
G) C) and D)

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