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The acid dissociation constant Ka equals 1.26 × 10-2 for HSO4- and is 5.6 × 10-10 for NH4+. Which statement about the following equilibrium is correct? HSO4-(aq) + NH3(aq) The acid dissociation constant Ka equals 1.26 × 10<sup>-</sup><sup>2</sup> for HSO<sub>4</sub><sup>-</sup> and is 5.6 × 10<sup>-</sup><sup>10</sup> for NH<sub>4</sub><sup>+</sup>. Which statement about the following equilibrium is correct? HSO<sub>4</sub><sup>-</sup>(aq) + NH<sub>3</sub>(aq)    SO<sub>4</sub><sup>2</sup><sup>-</sup>(aq) + NH<sub>4</sub><sup>+</sup>(aq)  A) The reactants will be favored because ammonia is a stronger base than the sulfate anion. B) The products will be favored because the hydrogen sulfate ion is a stronger acid than the ammonium ion. C) Neither reactants nor products will be favored because all of the species are weak acids or bases. D) The initial concentrations of the hydrogen sulfate ion and ammonia must be known before any prediction can be made. E) This reaction is impossible to predict,since the strong acid and the weak base appear on the same side of the equation. SO42-(aq) + NH4+(aq)


A) The reactants will be favored because ammonia is a stronger base than the sulfate anion.
B) The products will be favored because the hydrogen sulfate ion is a stronger acid than the ammonium ion.
C) Neither reactants nor products will be favored because all of the species are weak acids or bases.
D) The initial concentrations of the hydrogen sulfate ion and ammonia must be known before any prediction can be made.
E) This reaction is impossible to predict,since the strong acid and the weak base appear on the same side of the equation.

F) A) and B)
G) A) and C)

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Which represents a weak base B with Kb= 2 ×10-3? (Each circle represents 1.0 ×10-3 mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are not shown for clarity.)


A) Which represents a weak base B with K<sub>b</sub>= 2 ×10<sup>-</sup><sup>3</sup>? (Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are not shown for clarity.)  A)    B)    C)    D)    E)
B) Which represents a weak base B with K<sub>b</sub>= 2 ×10<sup>-</sup><sup>3</sup>? (Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are not shown for clarity.)  A)    B)    C)    D)    E)
C) Which represents a weak base B with K<sub>b</sub>= 2 ×10<sup>-</sup><sup>3</sup>? (Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are not shown for clarity.)  A)    B)    C)    D)    E)
D) Which represents a weak base B with K<sub>b</sub>= 2 ×10<sup>-</sup><sup>3</sup>? (Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are not shown for clarity.)  A)    B)    C)    D)    E)
E) Which represents a weak base B with K<sub>b</sub>= 2 ×10<sup>-</sup><sup>3</sup>? (Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of each box is 1.0 L.Solvent water molecules are not shown for clarity.)  A)    B)    C)    D)    E)

F) A) and B)
G) D) and E)

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Weak acids have weak conjugate bases.

A) True
B) False

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Consider the weak bases below and their Kb values: C6H7O- Kb = 1.3 × 10-10 C2H5NH2 Kb = 5.6 × 10-4 C5H5N Kb = 1.7 ×10-9 Arrange the conjugate acids of these weak bases in order of increasing acid strength.


A) C5H5NH+< C6H7OH < C2H5NH
B) C6H7OH < C5H5NH+ < C2H5NH
C) C5H5NH+< C2H5NH3+ < C6H7OH
D) C6H7OH < C2H5NH3+< C5H5NH+
E) C2H5NH3+< C5H5NH+ < C6H7OH

F) D) and E)
G) B) and C)

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Which aqueous solution has the highest pH?


A) 0.1 M CH3COOH,pKa = 4.7
B) 0.1 M CuCl2,pKa = 7.5
C) 0.1 M H3C6H5O7,pKa = 3.1
D) 0.1 M ZnCl2,pKa = 9.0
E) pure water

F) B) and C)
G) D) and E)

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What is the conjugate acid of the acetate ion?


A) CH3O2-
B) COOH
C) HC2H3O2
D) H2O
E) CH4

F) All of the above
G) None of the above

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Which one of the following is a strong acid?


A) H2CO3
B) H2SO3
C) H2SO4
D) H3PO4
E) CH3COOH

F) B) and E)
G) B) and D)

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Which one of the following is a strong acid?


A) CH3COOH
B) H2SO3
C) NH3
D) H3PO4
E) HClO3

F) D) and E)
G) None of the above

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Kw = 1.0 × 10-14 under all conditions.

A) True
B) False

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Amphoteric oxides are compounds that exhibit both acidic and basic behavior.

A) True
B) False

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In the reaction CaO(s) + SO2(g) In the reaction CaO(s) + SO<sub>2</sub>(g)    CaSO<sub>3</sub>(s) , A) O<sup>2</sup><sup>-</sup> acts as a Lewis base,and SO<sub>2</sub> acts as a Lewis acid. B) Ca<sup>2</sup><sup>+</sup> acts as a Lewis base,and SO<sub>4</sub><sup>2</sup><sup>-</sup> acts as a Lewis acid. C) SO<sub>3</sub><sup>2</sup><sup>-</sup> acts as a Lewis base,and SO<sub>2</sub> acts as a Lewis acid. D) SO<sub>2</sub> acts as a Lewis base,and O<sup>2</sup><sup>-</sup> acts as a Lewis acid. E) SO<sub>2</sub> acts as a Lewis base,and Ca<sup>2</sup><sup>+</sup> acts as a Lewis acid. CaSO3(s) ,


A) O2- acts as a Lewis base,and SO2 acts as a Lewis acid.
B) Ca2+ acts as a Lewis base,and SO42- acts as a Lewis acid.
C) SO32- acts as a Lewis base,and SO2 acts as a Lewis acid.
D) SO2 acts as a Lewis base,and O2- acts as a Lewis acid.
E) SO2 acts as a Lewis base,and Ca2+ acts as a Lewis acid.

F) A) and B)
G) A) and C)

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A solution is prepared by adding 0.10 mol of sodium fluoride,NaF,to 1.00 L of water.Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentrations of fluoride ions and sodium ions are equal.
E) The concentrations of hydronium ions and hydroxide ions are equal.

F) C) and D)
G) A) and D)

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Find the pH of a 0.20 M aqueous solution of dichloroacetic acid,for which Ka = 3.32 × 10-2.


A) 0.75
B) 2.71
C) 1.05
D) 2.35
E) 1.18

F) A) and C)
G) A) and E)

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Which is the strongest acid?


A) HBrO3
B) HFO3
C) HIO3
D) HClO3
E) All are of equal strength.

F) A) and D)
G) B) and D)

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Below is a representation of an aqueous solution of a weak acid HA at equilibrium.(Each circle represents 1.0 ×10-3 mol of atoms,and the volume of the box is 1.0 L.Solvent water molecules are not shown for clarity.) Below is a representation of an aqueous solution of a weak acid HA at equilibrium.(Each circle represents 1.0 ×10<sup>-</sup><sup>3</sup> mol of atoms,and the volume of the box is 1.0 L.Solvent water molecules are not shown for clarity.)    What is K<sub>a</sub> of HA? A) 1.0 ×10<sup>-</sup><sup>6</sup> B) 6.0 ×10<sup>-</sup><sup>3</sup> C) 2.5 ×10<sup>-</sup><sup>4</sup> D) 3.6 ×10<sup>-</sup><sup>5</sup> E) 1.0 ×10<sup>-</sup><sup>9</sup> What is Ka of HA?


A) 1.0 ×10-6
B) 6.0 ×10-3
C) 2.5 ×10-4
D) 3.6 ×10-5
E) 1.0 ×10-9

F) A) and E)
G) C) and E)

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Hard water deposits (calcium carbonate) have built up around your bathroom sink.Which of these substances would be most effective in dissolving the deposits?


A) ammonia
B) bleach (sodium hypochlorite)
C) lye (sodium hydroxide)
D) vinegar (acetic acid)

E) None of the above
F) A) and B)

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The substance (CH3CH2) 2NH is considered to be


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) C) and D)
G) All of the above

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What is [OH-] for a solution at 25°C that has [H3O+] = 2.35 × 10-3 M?


A) 4.26 × 10-5 M
B) 2.35 ×10-11 M
C) 4.26 × 10-12 M
D) 2.35 × 10-17 M
E) 2.35 ×10-3 M

F) B) and E)
G) A) and B)

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Which is a Lewis acid but not a Brønsted acid?


A) Fe3+
B) H3O+
C) HSO4-
D) NH3
E) H2O

F) C) and D)
G) D) and E)

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What is the pH of a 0.050 M LiOH solution?


A) 1.30
B) 3.00
C) 11.00
D) 12.39
E) 12.70

F) A) and E)
G) A) and D)

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