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A 25.0-mL sample of 0.10 M C2H5NH2 (ethylamine) is titrated with 0.15 M HCl.What is the pH of the solution after 9.00 mL of acid have been added to the amine? [Kb(C2H5NH2) = 6.5 × 10-4]


A) 11.08
B) 10.74
C) 10.81
D) 10.55
E) 10.49

F) B) and E)
G) A) and D)

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Calculate the pH at the equivalence point for the titration of 50.0 mL of 0.20 M NH3 with 0.20 M HCl. [Kb(NH3) = 1.8 × 10-5]


A) 2.87
B) 4.98
C) 5.13
D) 7.00
E) 11.13

F) C) and E)
G) All of the above

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Increasing the concentrations of the components of a buffer solution will increase the buffer capacity.

A) True
B) False

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Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H2A (0.10 M) with a strong base of the same concentration?


A) Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H<sub>2</sub>A (0.10 M) with a strong base of the same concentration? A)    B)    C)    D)    E)
B) Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H<sub>2</sub>A (0.10 M) with a strong base of the same concentration? A)    B)    C)    D)    E)
C) Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H<sub>2</sub>A (0.10 M) with a strong base of the same concentration? A)    B)    C)    D)    E)
D) Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H<sub>2</sub>A (0.10 M) with a strong base of the same concentration? A)    B)    C)    D)    E)
E) Which one of the following is the best representation of the titration curve which will be obtained in the titration of a weak diprotic acid H<sub>2</sub>A (0.10 M) with a strong base of the same concentration? A)    B)    C)    D)    E)

F) A) and E)
G) A) and D)

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Below is a representation of the sparingly soluble salt MX at equilibrium in aqueous solution.(Each circle represents 1.0 ×10-3 mol of atoms,and the volume of the box is 1.0 L.Solvent water molecules are omitted for clarity.) Below is a representation of the sparingly soluble salt MX at equilibrium in aqueous solution.(Each circle represents 1.0 ×10<sup>-3</sup> mol of atoms,and the volume of the box is 1.0 L.Solvent water molecules are omitted for clarity.)    What is K<sub>sp</sub> for MX? A) 1.5 ×10<sup>-5</sup> B) 6.0 ×10<sup>-6</sup> C) 3.6 ×10<sup>-1</sup> D) 1.8 ×10<sup>-3</sup> E) 9.0 ×10<sup>-6</sup> What is Ksp for MX?


A) 1.5 ×10-5
B) 6.0 ×10-6
C) 3.6 ×10-1
D) 1.8 ×10-3
E) 9.0 ×10-6

F) C) and D)
G) A) and C)

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Write the ion product expression for calcium phosphate,Ca3(P O4) 2.


A) Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) (3 × [Ca<sup>2+</sup>]) (2 × [P O<sub>4</sub><sup>3-</sup> ]
B) Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) (3 × [Ca<sup>2+</sup>]) (2 × [P O<sub>4</sub><sup>3-</sup> ]
C) Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) (3 × [Ca<sup>2+</sup>]) (2 × [P O<sub>4</sub><sup>3-</sup> ]
D) Write the ion product expression for calcium phosphate,Ca<sub>3</sub>(P O<sub>4</sub>) <sub>2</sub>. A)    B)    C)    D)    E) (3 × [Ca<sup>2+</sup>]) (2 × [P O<sub>4</sub><sup>3-</sup> ]
E) (3 × [Ca2+]) (2 × [P O43- ]

F) A) and C)
G) D) and E)

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Which is more soluble in a basic solution than in pure water?


A) AgF
B) AgCN
C) CO2
D) NaCl
E) CH3COOK

F) All of the above
G) A) and D)

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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of sodium cyanate (NaCNO) and 1.0 mole of cyanic acid (HCNO) in enough water to make 1.0 liter of solution. [Ka(HCNO) = 2.0 × 10-4]


A) 0.00
B) 3.00
C) 3.70
D) 4.40
E) 5.00

F) B) and D)
G) A) and C)

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What name is given to a solution that contains a weak acid and its conjugate base?

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