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What is the approximate value of the H-C-H bond angle in methane, CH4?


A) 90°
B) 109.5°
C) 120°
D) 180°

E) C) and D)
F) All of the above

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B

Avobenzone is an active ingredient in some common sunscreens. Which of the following is the correct molecular formula for avobenzone? Avobenzone is an active ingredient in some common sunscreens. Which of the following is the correct molecular formula for avobenzone?   A)  C<sub>22</sub>O<sub>22</sub>O<sub>3</sub> B)  C<sub>20</sub>H<sub>22</sub>O<sub>3</sub> C)  C<sub>21</sub>H<sub>23</sub>O<sub>3</sub> D)  C<sub>20</sub>H<sub>24</sub>O<sub>3</sub>


A) C22O22O3
B) C20H22O3
C) C21H23O3
D) C20H24O3

E) A) and B)
F) B) and C)

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Which of the following statements about electronegativity and the periodic table is true?


A) Electronegativity decreases across a row of the periodic table.
B) Electronegativity increases down a column of the periodic table.
C) Electronegativity increases across a row of the periodic table.
D) Electronegativity does not change down a column of the periodic table.

E) A) and D)
F) A) and C)

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Which of the following molecules has nonpolar covalent bonds?


A) HCl
B) N2
C) CHCl3
D) NO

E) A) and B)
F) A) and C)

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What is the order of decreasing bond length for a C-C bond comprised of the following molecular orbitals? sp3sp3sp2sp2spsp I  II  III \begin{array} { c c c } s p ^ { 3 } - s p ^ { 3 } & s p ^ { 2 } - s p ^ { 2 } & s p - s p \\\text { I } & \text { II } & \text { III }\end{array}


A) I > III > II
B) I > II > III
C) III > II > I
D) II > III > I

E) B) and D)
F) None of the above

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Which atomic orbitals overlap to form the C-H bonding molecular orbitals of ethane, CH3CH3?


A) Csp2 + H1s
B) Csp3 + H1s
C) C2p + H1s
D) Csp + H1s

E) None of the above
F) B) and D)

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Which of the following statements about constitutional isomers is true?


A) Constitutional isomers are different molecules having different molecular formula.
B) Constitutional isomers are different molecules having same molecular formula.
C) Constitutional isomers are same molecules having different molecular formula.
D) Constitutional isomers are same molecules having the same molecular formula.

E) None of the above
F) All of the above

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What is the hybridization of the carbon atom in the methyl cation, (CH3+) ?


A) sp3
B) sp2
C) sp
D) p

E) B) and C)
F) A) and B)

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What is the ground-state electronic configuration of a magnesium cation (Mg2+) ?


A) 1s2, 2s2, 2p6
B) 1s2, 2s2, 2p6, 3s1
C) 1s2, 2s2, 2p6, 3s2
D) 1s2, 2s2, 2p6, 3s2, 3p2

E) A) and C)
F) B) and C)

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A

Which of the following compounds has an atom with an unfilled valence shell of electrons?


A) H2O
B) BCl3
C) CH4
D) CO2

E) A) and B)
F) C) and D)

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In which of the following ions does carbon have a formal charge? [(CH3) 4 N]+\left[ \left( \mathrm { CH } _ { 3 } \right) _ { 4 } \mathrm {~N} \right] ^ { + }\quad[CH3CO2]\left[ \mathrm { CH } _ { 3 } \mathrm { CO } _ { 2 } \right] ^ { - }\quad[CH3OH2]+\left[ \mathrm { CH } _ { 3 } \mathrm { OH } _ { 2 } \right] ^ { + } \quad I \quad\quad\quad\quad\quad\quad\quad\quad II \quad\quad\quad\quad\quad III


A) I
B) II
C) III
D) None of the above

E) B) and D)
F) B) and C)

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What is the approximate C-C-C bond angle in propene, CH3CH=CH2?


A) 90°
B) 109.5°
C) 120°
D) 180°

E) B) and C)
F) A) and C)

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How many different isomers are there for a compound having the molecular formula C3H6O?


A) 4
B) 5
C) 6
D) 7

E) B) and C)
F) All of the above

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Which of the following covalent bonds has the largest dipole moment?


A) C-H
B) C-C
C) C-O
D) H-F

E) A) and B)
F) A) and C)

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Which atomic orbitals overlap to form the C-H bonding molecular orbitals of ethylene, H2C=CH2?


A) C2p + H1s
B) Csp + H1s
C) Csp3 + H1s
D) Csp2 + H1s

E) A) and B)
F) A) and C)

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In which of the following ions does carbon have a formal charge? CH3OH\mathrm { CH } _ { 3 } \mathrm { OH }\quadNaCH3\mathrm { NaCH } _ { 3 }\quadCH3CO2\mathrm { CH } _ { 3 } \mathrm { CO } _ { 2 } - I \quad\quad\quad\quad\quad II \quad\quad\quad\quad III


A) I
B) II
C) III
D) None of the above

E) None of the above
F) A) and B)

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How many constitutional isomers are there for a molecule having the molecular C3H8O?


A) 1
B) 2
C) 3
D) 4

E) B) and D)
F) C) and D)

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Which of the following pair does not represent resonance structures? Which of the following pair does not represent resonance structures?   A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

E) B) and C)
F) A) and B)

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What is the hybridization for each of the indicated atoms in the following compound? What is the hybridization for each of the indicated atoms in the following compound?   A)  I = sp<sup>2</sup>; II = sp<sup>2</sup>; III = sp<sup>2</sup>. B)  I = sp<sup>2</sup>; II = sp<sup>3</sup>; III = sp<sup>3</sup>. C)  I = sp; II = sp<sup>2</sup>; III = sp<sup>3</sup>. D)  I = sp<sup>2</sup>; II = sp<sup>2</sup>; III = sp<sup>3</sup>.


A) I = sp2; II = sp2; III = sp2.
B) I = sp2; II = sp3; III = sp3.
C) I = sp; II = sp2; III = sp3.
D) I = sp2; II = sp2; III = sp3.

E) A) and B)
F) A) and C)

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D

Follow the curved arrows to draw the second resonance structure for the ion below. Follow the curved arrows to draw the second resonance structure for the ion below.   A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

E) A) and C)
F) All of the above

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