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Atoms with the same number of protons but different numbers of neutrons are called ________.

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What kind of molecular orbital (σ, σ*, π, or π*)results when the two atomic orbitals shown below interact in the manner indicated? What kind of molecular orbital (σ, σ*, π, or π*)results when the two atomic orbitals shown below interact in the manner indicated?

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Draw the shape of a 2p orbital.

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Ar, K+, Cl- are isoelectronic elements (elements with the same number of electrons). What orbital does the last electron occupy?

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3p orbital

Give the H-C-H bond angle in H2CO.


A) 60
B) 90
C) 109.5
D) 120
E) 180

F) A) and B)
G) A) and C)

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Which of the following molecules does not exhibit a net dipole moment of zero?


A) CO2
B) CH4
C) CCl4
D) H2O
E) SO3

F) All of the above
G) B) and E)

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What are the formal charges on nitrogen and the starred oxygen atom in the following molecule? What are the formal charges on nitrogen and the starred oxygen atom in the following molecule?   A) N = -1, O = 0 B) N = +1, O = -1 C) N = +1, O = +1 D) N = -1, O = -1 E) N= +1, O = 0


A) N = -1, O = 0
B) N = +1, O = -1
C) N = +1, O = +1
D) N = -1, O = -1
E) N= +1, O = 0

F) C) and D)
G) All of the above

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The N-H single bond in methyl amine (CH3NH2) is a ________ bond formed by the overlap of a(n) ________ orbital on N and a(n) ________ orbital on H.


A) σ; sp2; s
B) σ ; sp3; s
C) π ; sp3; s
D) π ; sp2; p
E) π ; p ; p

F) D) and E)
G) C) and E)

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Which of the following statements correctly describes the third electron shell that surrounds the nucleus of an atom?


A) The third shell contains only s and p atomic orbitals.
B) The maximum number of electrons that can occupy the third shell is 18.
C) The total number of atomic orbitals present in the third shell is 16.
D) The third shell can contain f orbitals.
E) All third shell elements must have d electrons.

F) A) and B)
G) C) and E)

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B

Identify the compound(s) that have a nonzero dipole moment.


A) CH3NH2
B) CO2
C) CH3OCH3
D) (CH3) 2C Identify the compound(s) that have a nonzero dipole moment. A) CH<sub>3</sub>NH<sub>2</sub> B) CO<sub>2</sub> C) CH<sub>3</sub>OCH<sub>3</sub> D) (CH<sub>3</sub>) <sub>2</sub>C   C(CH<sub>3</sub>) <sub>2</sub> E) BCl<sub>3</sub> C(CH3) 2
E) BCl3

F) D) and E)
G) None of the above

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What is the CNN bond angle in the compound shown below? What is the CNN bond angle in the compound shown below?   A) ~60° B) ~90° C) ~110° D) ~120° E) ~180°


A) ~60°
B) ~90°
C) ~110°
D) ~120°
E) ~180°

F) A) and E)
G) C) and D)

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The hydrogen-halogen bond becomes ________ and ________ as the size (atomic weight) of the halogen increases.


A) longer, weaker
B) longer, stronger
C) shorter, weaker
D) shorter, stronger

E) A) and B)
F) None of the above

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Give the electronic configuration for N-3.


A) 1s22s2
B) 1s22s22p3
C) 1s22s22p4
D) 1s22s22p6
E) 1s22s22p63s1

F) B) and C)
G) B) and D)

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Draw the Lewis structure for CH3N2+.

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Triethylamine [(CH3CH2) 3N] is a molecule in which the nitrogen atom is ________ hybridized and the CNC bond angle is ________.


A) sp2, >109.5°
B) sp2, <109.5°
C) sp3, >109.5°
D) sp3, <109.5°
E) sp, 109.5°

F) A) and B)
G) None of the above

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How many sp2 hybridized carbons are present in allene (H2C=C=CH2) ?


A) 0
B) 1
C) 1) 5
D) 2
E) 3

F) A) and B)
G) A) and C)

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Using the symbol δ+and δ-, show the direction of the polarity in the indicated bond. Using the symbol δ+and δ-, show the direction of the polarity in the indicated bond.

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Consider the interaction of two hydrogen 1s atomic orbitals of the same phase. Which of the statements below is an incorrect description of this interaction?


A) A sigma bonding molecular orbital is formed.
B) The molecular orbital formed is lower in energy than a hydrogen 1s atomic orbital.
C) The molecular orbital formed has a node between the atoms.
D) The molecular orbital formed is cylindrically symmetric.
E) A maximum of two electrons may occupy the molecular orbital formed.

F) A) and C)
G) A) and B)

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Draw the Kekulé structure and show the direction of the dipole moment for CH2Cl2.

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11ea7d6e_065f_12e3_8568_a34d445fb275_TB1830_00_TB1830_00

Draw condensed structures for the four compounds with formula C3H9N.

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CH3CH2CH2NH2
C...

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