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The specific heat of liquid ethanol, C2H5OH(l) , is 2.46 J/g·°C and the heat of vaporization is 39.3 kJ/mol.The boiling point of ethanol is 78.3 °C.What amount of enthalpy is required to heat 50.0 g of liquid ethanol from 23.0 °C to ethanol vapor at 78.3 °C?


A) 42.7 kJ
B) 49.5 kJ
C) 179 kJ
D) 1970kJ
E) 6840 kJ

F) D) and E)
G) All of the above

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Which of the following atoms does not participate in hydrogen bonding?


A) S
B) O
C) F
D) N

E) All of the above
F) None of the above

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Suppose the atoms in a two-dimensional crystal have the following arrangement: Suppose the atoms in a two-dimensional crystal have the following arrangement:   How many atoms are in one unit cell? How many atoms are in one unit cell?

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one (each corner of ...

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The triple point of iodine is at 0.12 atm and 115°C. Thus, liquid I2


A) is more dense than I2 (s) .
B) cannot exist above 115°C.
C) is liquid at room temperature.
D) cannot have a vapor pressure less than 91 torr.

E) None of the above
F) A) and D)

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The freezing point of a liquid does not change as the atmospheric pressure changes.

A) True
B) False

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Which of the following substances would have the highest critical temperature?


A) CH3Cl
B) C2H6
C) F2
D) H2
E) CO2

F) A) and D)
G) B) and C)

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The molar heats of sublimation and fusion of iodine are 62.3 kJ/mol and15.3 kJ/mol, respectively. Calculate the molar heat of vaporization of liquid iodine.


A) 77.6 kJ/mol
B) 47.0 kJ/mol
C) -47.0 kJ/mol
D) -77.6 kJ/mol
E) 4.07 kJ/mol

F) A) and B)
G) C) and D)

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The shape of the water-to-glass meniscus results from the strong adhesive forces between glass and water.

A) True
B) False

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Identify the dominant (strongest)type of intermolecular force present in RbCl(s).

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Which of the following properties indicates the presence of weak intermolecular forces in a liquid?


A) a high heat of vaporization
B) a high critical temperature
C) a high vapor pressure
D) a high boiling point
E) None of the above.

F) D) and E)
G) A) and B)

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Indicate all the types of intermolecular forces of attraction in CF4(g).

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Of the given pair of compounds, which would have the higher boiling point? NH3 or CH4

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Which one of the following elements would have the lowest melting point?


A) Kr
B) Br2
C) S8
D) Ca
E) K

F) C) and D)
G) A) and B)

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Which of the following would be expected to have the highest vapor pressure at room temperature?


A) ethanol, bp = 78°C
B) methanol, bp = 65°C
C) water, bp = 100°C
D) acetone, bp = 56°C

E) B) and C)
F) A) and D)

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Which one of the following substances should exhibit hydrogen bonding in the liquid state?


A) SiH4
B) H2
C) H2S
D) CH4
E) CH3NH2

F) B) and D)
G) All of the above

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Methane has a heat of fusion of 0.84 kJ/mol and a heat of vaporization of 9.2 kJ/mol.Estimate the value for the heat of sublimation.

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The meniscus for water is curved upward at the edges (i.e., it is "concave up"). Explain this phenomenon in terms of cohesion and adhesion.

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Adhesion of water to...

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Crystals of elemental sulfur are easily crushed, and melt at 113°C.Liquid sulfur does not conduct electricity.What kind of crystal is this?

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Vanadium crystallizes in a body-centered cubic lattice, and the length of the edge of a unit cell is 305 pm. What is the density of V?


A) 5.96 g/cm3
B) 2.98 g/cm3
C) 2.98 * 10-6 g/cm3
D) 5.96 * 10-30 g/cm3
E) 11.9 g/cm3

F) B) and E)
G) C) and D)

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Given the following compound and its boiling point, identify whether it is polar or nonpolar: Ar, -185.7°C.

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