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If the system 3H2(g) + N2(g) If the system 3H<sub>2</sub>(g) + N<sub>2</sub>(g)   2NH<sub>3</sub>(g) is at equilibrium and more N<sub>2</sub> is added, a net reaction that consumes some of the added N<sub>2</sub> will occur until a new equilibrium is reached. 2NH3(g) is at equilibrium and more N2 is added, a net reaction that consumes some of the added N2 will occur until a new equilibrium is reached.

A) True
B) False

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True

Which reaction shown will have the highest concentration of products at equilibrium?


A) Which reaction shown will have the highest concentration of products at equilibrium? A)    B)    C)    D)    E)
B) Which reaction shown will have the highest concentration of products at equilibrium? A)    B)    C)    D)    E)
C) Which reaction shown will have the highest concentration of products at equilibrium? A)    B)    C)    D)    E)
D) Which reaction shown will have the highest concentration of products at equilibrium? A)    B)    C)    D)    E)
E) Which reaction shown will have the highest concentration of products at equilibrium? A)    B)    C)    D)    E)

F) A) and B)
G) C) and E)

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Hydrogen peroxide may decompose to form water and oxygen gas according to the following reaction. 2H2O2(g) Hydrogen peroxide may decompose to form water and oxygen gas according to the following reaction. 2H<sub>2</sub>O<sub>2</sub>(g)    2H<sub>2</sub>O(g)  + O<sub>2</sub>(g)  In a particular experiment, 1.75 moles of H<sub>2</sub>O<sub>2</sub> were placed in a 2.5-L reaction chamber at 307ºC.After equilibrium was reached, 1.20 moles of H<sub>2</sub>O<sub>2</sub> remained.What is K for the reaction? A) 2.0 × 10<sup>−4</sup> B) 2.3 × 10<sup>−2</sup> C) 2.4 × 10<sup>-3</sup> D) 5.5 × 10<sup>−3</sup> E) 3.9 × 10<sup>−4</sup> 2H2O(g) + O2(g) In a particular experiment, 1.75 moles of H2O2 were placed in a 2.5-L reaction chamber at 307ºC.After equilibrium was reached, 1.20 moles of H2O2 remained.What is K for the reaction?


A) 2.0 × 10−4
B) 2.3 × 10−2
C) 2.4 × 10-3
D) 5.5 × 10−3
E) 3.9 × 10−4

F) B) and E)
G) A) and E)

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B

At 450°C, tert-butyl alcohol decomposes into water and isobutene.(CH3) 3COH(g) At 450°C, tert-butyl alcohol decomposes into water and isobutene.(CH<sub>3</sub>) <sub>3</sub>COH(g)    (CH<sub>3</sub>) <sub>2</sub>CCH<sub>2</sub>(g)  + H<sub>2</sub>O(g)  A reaction vessel contains these compounds at equilibrium.What will happen if the volume of the container is reduced by 50% at constant temperature? A) The forward reaction will proceed in order to reestablish equilibrium. B) The reverse reaction will proceed in order to reestablish equilibrium. C) No change occurs. D) The equilibrium constant will increase. E) The equilibrium constant will decrease. (CH3) 2CCH2(g) + H2O(g) A reaction vessel contains these compounds at equilibrium.What will happen if the volume of the container is reduced by 50% at constant temperature?


A) The forward reaction will proceed in order to reestablish equilibrium.
B) The reverse reaction will proceed in order to reestablish equilibrium.
C) No change occurs.
D) The equilibrium constant will increase.
E) The equilibrium constant will decrease.

F) A) and B)
G) A) and C)

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Which reaction shown will have the highest concentration of reactants at equilibrium?


A) Which reaction shown will have the highest concentration of reactants at equilibrium? A)    B)    C)    D)    E)
B) Which reaction shown will have the highest concentration of reactants at equilibrium? A)    B)    C)    D)    E)
C) Which reaction shown will have the highest concentration of reactants at equilibrium? A)    B)    C)    D)    E)
D) Which reaction shown will have the highest concentration of reactants at equilibrium? A)    B)    C)    D)    E)
E) Which reaction shown will have the highest concentration of reactants at equilibrium? A)    B)    C)    D)    E)

F) C) and E)
G) B) and C)

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A 6.0-L vessel was found to contain 1.0 mol BrCl3, 2.0 mol Br2 and 6.0 mol Cl2.What is the equilibrium constant, K, for this equilibrium mixture for the reaction 2BrCl3(g) A 6.0-L vessel was found to contain 1.0 mol BrCl3, 2.0 mol Br2 and 6.0 mol Cl2.What is the equilibrium constant, K, for this equilibrium mixture for the reaction 2BrCl3(g)    Br2(g)  + 3Cl2(g) ? A) 0.014 B) 108 C) 18 D) 12 E) 432 Br2(g) + 3Cl2(g) ?


A) 0.014
B) 108
C) 18
D) 12
E) 432

F) C) and E)
G) B) and E)

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Compounds A, B, and C react according to the following equation.3A(g) + 2B(g) Compounds A, B, and C react according to the following equation.3A(g)  + 2B(g)    2C(g)  At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M, [B] = 1.23 M, and [C] = 1.75 M.What is the value of K for this reaction? A) 0.309 B) 0.601 C) 1.66 D) 2.25 E) 3.24 2C(g) At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M, [B] = 1.23 M, and [C] = 1.75 M.What is the value of K for this reaction?


A) 0.309
B) 0.601
C) 1.66
D) 2.25
E) 3.24

F) A) and C)
G) B) and D)

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For the nitrogen fixation reaction, 3H2(g) + N2(g) For the nitrogen fixation reaction, 3H<sub>2</sub>(g)  + N<sub>2</sub>(g)    2NH<sub>3</sub>(g) , K = 6.0 × 10<sup>−2</sup> at 500°C.If 0.250 M H<sub>2</sub> and 0.050 M NH<sub>3</sub> are present at equilibrium, what is the equilibrium concentration of N<sub>2</sub>? A) 3.3 M B) 2.7 M C) 0.20 M D) 0.083 M E) 0.058 M 2NH3(g) , K = 6.0 × 10−2 at 500°C.If 0.250 M H2 and 0.050 M NH3 are present at equilibrium, what is the equilibrium concentration of N2?


A) 3.3 M
B) 2.7 M
C) 0.20 M
D) 0.083 M
E) 0.058 M

F) All of the above
G) A) and D)

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The equilibrium constant expression for the reaction CuO(s) + H2(g) The equilibrium constant expression for the reaction CuO(s) + H<sub>2</sub>(g)   Cu(s) + H<sub>2</sub>O(g) is K = [H<sub>2</sub>]/[H<sub>2</sub>O]. Cu(s) + H2O(g) is K = [H2]/[H2O].

A) True
B) False

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At elevated temperatures, hydrogen iodide may decompose to form hydrogen gas and iodine gas, as follows. 2HI(g) At elevated temperatures, hydrogen iodide may decompose to form hydrogen gas and iodine gas, as follows. 2HI(g)    H<sub>2</sub>(g)  + I<sub>2</sub>(g)  In a particular experiment, the concentrations at equilibrium were measured to be [HI] = 0.85 mol/L, [I<sub>2</sub>] = 0.60 mol/L, and [H<sub>2</sub>] = 0.27 mol/L.What is K for the above reaction? A) 5.3 B) 0.22 C) 4.5 D) 0.19 E) 1.6× 10<sup>2</sup> H2(g) + I2(g) In a particular experiment, the concentrations at equilibrium were measured to be [HI] = 0.85 mol/L, [I2] = 0.60 mol/L, and [H2] = 0.27 mol/L.What is K for the above reaction?


A) 5.3
B) 0.22
C) 4.5
D) 0.19
E) 1.6× 102

F) A) and D)
G) A) and C)

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Determine the balanced chemical equation that corresponds to the given equilibrium expression. Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)


A) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
B) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
C) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
D) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
E) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)

F) A) and E)
G) B) and C)

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Which substances are included in the equilibrium constant expression, Kc?


A) Only pure solids
B) Only pure liquids
C) Only pure solids and liquids
D) Only gases and dissolved substances
E) All participating substances

F) D) and E)
G) B) and D)

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Write the equilibrium constant expression for the reaction shown. Write the equilibrium constant expression for the reaction shown.   A)    B)    C)    D)    E)


A) Write the equilibrium constant expression for the reaction shown.   A)    B)    C)    D)    E)
B) Write the equilibrium constant expression for the reaction shown.   A)    B)    C)    D)    E)
C) Write the equilibrium constant expression for the reaction shown.   A)    B)    C)    D)    E)
D) Write the equilibrium constant expression for the reaction shown.   A)    B)    C)    D)    E)
E) Write the equilibrium constant expression for the reaction shown.   A)    B)    C)    D)    E)

F) B) and C)
G) A) and B)

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When a reaction system reaches equilibrium, the forward and reverse reactions stop.

A) True
B) False

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False

A mixture of 0.500 mole of carbon monoxide and 0.400 mole of bromine was placed into a rigid 1.00-L container and the system was allowed to come to equilibrium.The equilibrium concentration of COBr2 was 0.233 M.What is K for this reaction? CO(g) + Br2(g) A mixture of 0.500 mole of carbon monoxide and 0.400 mole of bromine was placed into a rigid 1.00-L container and the system was allowed to come to equilibrium.The equilibrium concentration of COBr<sub>2</sub> was 0.233 M.What is K for this reaction? CO(g)  + Br<sub>2</sub>(g)    COBr<sub>2</sub>(g)  A) 5.23 B) 2.14 C) 1.17 D) 0.467 E) 0.191 COBr2(g)


A) 5.23
B) 2.14
C) 1.17
D) 0.467
E) 0.191

F) A) and D)
G) All of the above

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Write the equilibrium constant expression for the reaction shown. 2NOCl(g) ⇌ 2NO(g) + Cl2(g)


A) Write the equilibrium constant expression for the reaction shown. 2NOCl(g)   ⇌ 2NO(g)  + Cl<sub>2</sub>(g)  A)    B)    C)    D)    E)
B) Write the equilibrium constant expression for the reaction shown. 2NOCl(g)   ⇌ 2NO(g)  + Cl<sub>2</sub>(g)  A)    B)    C)    D)    E)
C) Write the equilibrium constant expression for the reaction shown. 2NOCl(g)   ⇌ 2NO(g)  + Cl<sub>2</sub>(g)  A)    B)    C)    D)    E)
D) Write the equilibrium constant expression for the reaction shown. 2NOCl(g)   ⇌ 2NO(g)  + Cl<sub>2</sub>(g)  A)    B)    C)    D)    E)
E) Write the equilibrium constant expression for the reaction shown. 2NOCl(g)   ⇌ 2NO(g)  + Cl<sub>2</sub>(g)  A)    B)    C)    D)    E)

F) All of the above
G) B) and D)

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What is defined as a fraction with equilibrium product concentrations in the numerator and equilibrium reactant concentrations in the denominator and each concentration raised to a power equal to the corresponding stoichiometric coefficient in the balanced chemical equation?


A) Reversibility expression
B) Reaction expression
C) Equilibrium expression
D) Product quotient
E) Mass action

F) A) and B)
G) None of the above

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When the following reaction is at equilibrium 2NOCl(g) When the following reaction is at equilibrium 2NOCl(g)   2NO(g) + Cl<sub>2</sub>(g) then [NO]<sup>2</sup> [Cl<sub>2</sub>] = K [NOCl]<sup>2</sup>. 2NO(g) + Cl2(g) then [NO]2 [Cl2] = K [NOCl]2.

A) True
B) False

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At 35ºC, the equilibrium constant for the reaction 2NOCl(g) At 35ºC, the equilibrium constant for the reaction 2NOCl(g)    2NO(g)  + Cl<sub>2</sub>(g)  is K = 1.6 × 10<sup>−5</sup>.An equilibrium mixture was found to have the following concentrations of Cl<sub>2</sub> and NOCl: [Cl<sub>2</sub>] = 1.2 × 10<sup>−2</sup> M; [NOCl] = 2.8 × 10<sup>−1</sup> M.Calculate the concentration of NO(g)  at equilibrium. A) 1.0 × 10<sup>−4</sup> M B) 1.0 × 10<sup>−2</sup> M C) 2.8 × 10<sup>−1</sup> M D) 2.4 × 10<sup>−2</sup> M E) 1.6 × 10<sup>−3</sup> M 2NO(g) + Cl2(g) is K = 1.6 × 10−5.An equilibrium mixture was found to have the following concentrations of Cl2 and NOCl: [Cl2] = 1.2 × 10−2 M; [NOCl] = 2.8 × 10−1 M.Calculate the concentration of NO(g) at equilibrium.


A) 1.0 × 10−4 M
B) 1.0 × 10−2 M
C) 2.8 × 10−1 M
D) 2.4 × 10−2 M
E) 1.6 × 10−3 M

F) D) and E)
G) A) and B)

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Determine the balanced chemical equation that corresponds to the given equilibrium expression. Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)


A) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
B) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
C) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
D) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)
E) Determine the balanced chemical equation that corresponds to the given equilibrium expression.   A)    B)    C)    D)    E)

F) C) and E)
G) C) and D)

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