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An aqueous solution is prepared by dissolving the salt formed by the neutralization of a weak acid by a weak base. Which statement about the solution is correct?


A) The solution is strongly basic.
B) The solution is weakly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for K a and K b for the species in solution must be known before a prediction can be made.

F) A) and D)
G) B) and D)

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What is the pH of a 0.0125 M NaOH solution?


A) 0.972
B) 1.903
C) 12.097
D) 13.028
E) None of these choices are correct.

F) A) and B)
G) A) and E)

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What is the pH of a 0.050 M triethylamine, (C2H5) 3N, solution?Kb for triethylamine is 5.3 × 104.


A) 11.69
B) 8.68
C) 5.32
D) 2.31
E) < 2.0

F) A) and E)
G) B) and C)

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Aqueous solutions of phosphoric acid and sodium nitrite are combined, and the following equilibrium is established. H3PO4(aq) + NO2(aq) ⇄ H2PO4(aq) + HNO2(aq) The equilibrium constant Kc for this reaction is greater than one. Based on this information, which of the following statements is correct?


A) Phosphoric acid is a weaker acid than nitrous acid.
B) Nitrous acid is a weaker acid than water.
C) The nitrite anion is a weaker base than the dihydrogen phosphate anion.
D) The dihydrogen phosphate anion is a stronger acid than nitrous acid.
E) Phosphoric acid is a stronger acid than nitrous acid.

F) C) and D)
G) A) and E)

Correct Answer

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Which of the following is a Lewis base?


A) BCl 3
B) Cu 2+
C) Cl
D) Mn 2+
E) NH 4 +

F) All of the above
G) C) and D)

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Which of the following is considered a Lewis acid?


A) CH 3NH 2
B) BCl 3
C) F
D) BF 4
E) CH 4

F) A) and B)
G) B) and E)

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Iodine trichloride, ICl3, will react with a chloride ion to form ICl4. Which species, if any, acts as a Lewis acid this reaction?


A) ICl 4
B) ICl 3
C) Cl
D) The solvent
E) None of these choices are correct.

F) A) and B)
G) B) and D)

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What is the pH of a 0.75 M HNO3 solution?


A) 0.12
B) 0.29
C) 0.63
D) 0.82
E) > 1.0

F) None of the above
G) B) and D)

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An aqueous solution is considered to be acidic if


A) the hydroxide ion concentration is 10 6 M.
B) the hydrogen ion concentration is 10 8 M.
C) the hydroxide and hydrogen ion concentrations are equal.
D) the hydroxide ion concentration is greater than the hydrogen ion concentration.
E) the hydroxide ion concentration is 10 10 M.

F) A) and C)
G) B) and C)

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What is the [OH] for a solution at 25°C that has [H3O+] = 2.35 × 103 M?


A) 4.26 × 10 5 M
B) 2.35 × 10 11 M
C) 4.26 × 10 12 M
D) 2.35 × 10 17 M
E) None of these choices are correct.

F) All of the above
G) C) and D)

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What is the [OH] for a solution at 25°C that has [H3O+] = 8.23 × 102 M?


A) > 10 5 M
B) 1.22 × 10 6 M
C) 8.23 × 10 12 M
D) 1.22 × 10 13 M
E) 8.23 × 10 16 M

F) C) and E)
G) C) and D)

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What is the [OH] for a solution at 25°C that has pH = 4.29?


A) 1.4 × 10 2 M
B) 5.l × 10 5 M
C) 1.9 × 10 10 M
D) 7.3 × 10 13 M
E) 9.71 M

F) B) and C)
G) C) and D)

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A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct? H2C2O4(aq) + H2PO4(aq) ⇄ HC2O4(aq) + H3PO4(aq)


A) Oxalic acid is a weaker acid than phosphoric acid.
B) The hydrogen oxalate anion, HC 2O 4, is a stronger base than the dihydrogen phosphate anion, H 2PO 4.
C) Phosphoric acid is a weaker acid than oxalic acid.
D) The dihydrogen phosphate anion, H 2PO 4 , is a stronger acid than oxalic acid.
E) Water is a stronger acid than either oxalic or phosphoric acids.

F) B) and C)
G) C) and D)

Correct Answer

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What is the pOH of a 0.0250 M HI solution?


A) 0.944
B) 1.602
C) 12.398
D) 13.056
E) None of these choices are correct.

F) D) and E)
G) A) and E)

Correct Answer

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Which one of the following is a strong acid?


A) H 2CO 3
B) H 2SO 3
C) H 2SO 4
D) H 3PO 4
E) CH 3COOH

F) A) and E)
G) All of the above

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Butyric acid is responsible for the odor in rancid butter. A solution of 0.25 M butyric acid has a pH of 2.71. What is the Ka for the acid?


A) 0.36
B) 2.4 × 10 2
C) 7.8 × 10 3
D) 1.5 × 10 5
E) None of these choices are correct.

F) C) and D)
G) None of the above

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In applying molecular orbital theory, the bond order is calculated in the same way as with Lewis structures.

A) True
B) False

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In order to be a Brønsted-Lowry base, a species must contain a proton.

A) True
B) False

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A solution is prepared by adding 0.10 mol of potassium acetate, KCH3COO, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The concentrations of potassium ions and acetate ions will be identical.
E) The concentration of acetate ions will be greater than the concentration of potassium ions.

F) A) and B)
G) A) and C)

Correct Answer

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What is the pH of a 0.0035 M KOH solution?


A) 2.46
B) 5.65
C) 8.35
D) 11.54
E) None of these choices are correct.

F) None of the above
G) A) and B)

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