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Select the element with the lowest first ionization energy.


A) Se
B) S
C) Sn
D) Sr
E) H

F) B) and D)
G) A) and C)

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elements from Li to Cs?


A) metallic character decreases
B) electronegativity increases
C) melting point increases
D) first ionization energy increases
E) chemical reactivity increases

F) C) and D)
G) A) and E)

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Which of the following statements about the effective nuclear charge, Zeff, is correct?


A) Zeff increases with the size of the atom.
B) Zeff decreases across a period and increases down a group.
C) Zeff increases across a period and is relatively constant down a group.
D) Zeff increases as the value of the principal quantum number increases.
E) Zeff is greater for hydrogen than for any other element.

F) A) and B)
G) D) and E)

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Thallium can form two oxides, Tl2O and Tl2O3. Which will be the more basic substance?


A) Tl2O
B) Tl2O3
C) They have the same strength as bases.
D) Neither compound has any acidic or basic properties.
E) More information is needed to make an accurate prediction.

F) None of the above
G) C) and E)

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Silicon halides have stronger bonds than corresponding carbon halides. Which of the following is a possible explanation of this phenomenon?


A) The larger silicon atoms permit better overlap of its atomic orbitals with those of the halogens than the smaller carbons atoms do.
B) The large electronegativity difference between silicon and the halogens makes their bonds stronger than those of carbon.
C) Silicon has the ability to form a partial double bond with a halogen through the overlap of its d-orbital with a p-orbital of the halogen.
D) Silicon has a larger effective nuclear charge than carbon which allows it to bond more strongly to the more negative halogens than carbon.
E) Carbon-halogen bonds are unusually weak.

F) A) and D)
G) B) and C)

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Which element forms compounds which are used to treat individuals suffering from manic-depressive disorders?


A) fluorine
B) lithium
C) boron
D) beryllium
E) arsenic

F) A) and E)
G) A) and B)

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The elements from Groups 1A(1) and 2A(2) are


A) strong acids.
B) strong bases.
C) amphoteric.
D) strong oxidizing agents.
E) strong reducing agents.

F) C) and D)
G) B) and E)

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Phosphoric acid (H3PO4) is a strong acid.

A) True
B) False

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The smallest ionization energies are found in the ____________ ___________ region of the periodic table.


A) upper right
B) upper left
C) lower right
D) lower left
E) transition element (d-block)

F) C) and D)
G) A) and B)

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Certain Period 2 elements exhibit behaviors similar to Period 3 elements immediately below and to the right. One of these interesting diagonal relationships occurs between beryllium and aluminum. Which of the following is one of their differences?


A) Some aluminum compounds and all beryllium compounds show significant covalent character in the gas phase.
B) Beryllium forms bridge bonds in its hydrides while aluminum does not.
C) Both form oxides that are impervious to reaction with water.
D) The cations for both strongly polarize nearby electron clouds.
E) Beryllium occurs in nature as the uncombined element, whereas aluminum does not.

F) A) and C)
G) B) and E)

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What is the stable form of the element sulfur, at room temperature?


A) atomic sulfur
B) S2
C) S4
D) S6
E) S8

F) A) and B)
G) A) and C)

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