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"The volume of an ideal gas is directly proportional to the number of moles of the gas at constant temperature and pressure" is a statement of _____________ Law.


A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Dalton's

F) A) and C)
G) C) and D)

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A weather balloon was initially at a pressure of 0.950 atm, and its volume was 35.0 L. The pressure decreased to 0.750 atm, without loss of gas or change in temperature. What was the change in the volume?


A) increased by 44.3 L
B) increased by 9.3 L
C) increased by 7.4 L
D) decreased by 27.6 L
E) decreased by 7.4 L

F) A) and B)
G) A) and C)

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Hydrogen peroxide was catalytically decomposed and 75.3 mL of oxygen gas was collected over water at 25 °\degree C and 742 torr. What mass of oxygen was collected? (Pwater = 24 torr at 25 °\degree C)


A) 0.00291 g
B) 0.0931 g
C) 0.0962 g
D) 0.0993 g
E) 0.962 g

F) A) and E)
G) A) and B)

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Freon-12, CF2Cl2, which has been widely used in air conditioning systems, is considered a threat to the ozone layer in the stratosphere. Calculate the root-mean-square velocity of Freon-12 molecules in the lower stratosphere where the temperature is -65 °\degree C.


A) 20 m/s
B) 120 m/s
C) 210 m/s
D) 260 m/s
E) 4.4 * 104 m/s

F) B) and E)
G) B) and D)

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Calculate the pressure of a helium sample at -207.3 °\degree C and 768 mL if it exerts a pressure of 175 kPa at 25.0 °\degree C and 925 mL.


A) 32.1 kPa
B) 46.6 kPa
C) 657 kPa
D) 953 kPa
E) None of these choices is correct since the pressure would have to be negative.

F) C) and D)
G) A) and B)

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For real gases, PV < nRT, always.

A) True
B) False

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Briefly state the conditions corresponding to STP (standard temperature and pressure).

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At STP, the pressure...

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A sample of ammonia gas at 65.5 °\degree C and 524 torr has a volume of 15.31 L. What is its volume when the temperature is -15.8 °\degree C and its pressure is 524 torr?


A) 3.69 L
B) 11.6 L
C) 20.2 L
D) 63.5 L
E) None of these choices is correct since the volume would have to be negative.

F) A) and B)
G) B) and E)

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A sample container of carbon monoxide occupies a volume of 435 mL at a pressure of 785 torr and a temperature of 298 K. What would its temperature be if the volume were changed to 265 mL at a pressure of 785 torr?


A) 182 K
B) 298 K
C) 387 K
D) 489 K
E) 538 K

F) A) and B)
G) All of the above

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For a gas obeying Boyle's Law, a plot of V versus 1/P will give a straight line passing through the origin.

A) True
B) False

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Calculate the temperature of an argon sample at 55.4 kPa and 18.6 L if it occupies 25.8 L at 75.0 °\degree C and 41.1 kPa.


A) 95.0 °\degree C
B) 85.1 °\degree C
C) 77.2 °\degree C
D) 72.9 °\degree C
E) 65.2 °\degree C

F) D) and E)
G) All of the above

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A 3.0-L sample of helium was placed in a container fitted with a porous membrane. Half of the helium effused through the membrane in 24 hours. A 3.0-L sample of oxygen was placed in an identical container. How many hours will it take for half of the oxygen to effuse through the membrane?


A) 8.5 h
B) 12 h
C) 48 h
D) 60. h
E) 68 h

F) B) and E)
G) C) and E)

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Use plots of PV/nRT versus P to show the behavior of an ideal gas and of typical real gases. Label the axes and show their scales.

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Ideal gas: the plot is a horizontal line...

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When a closed-ended manometer is used for pressure measurements, and the closed end is under vacuum, the level of manometer liquid in the closed arm can never be lower than that in the other arm.

A) True
B) False

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Assuming ideal behavior, what is the density of argon gas at STP, in g/L?


A) 0.0176 g/L
B) 0.0250 g/L
C) 0.0561 g/L
D) 1.78 g/L
E) 181. g/L

F) A) and B)
G) B) and E)

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Given that pressure has dimensions of force * area; that force has dimensions of mass * acceleration; and that the S.I. unit of pressure is the pascal, what is 1 pascal in terms of S.I. base units?


A) 1 Pa = 1000 g/cm*s2
B) 1 Pa = 1 g/m*s2
C) 1 Pa = 10¯3 kg*m/s2
D) 1 Pa = 1 kg*m/s2
E) 1 Pa = 1 kg/m*s2

F) C) and E)
G) B) and C)

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Magnesium metal (0.100 mol) and a volume of aqueous hydrochloric acid that contains 0.500 mol of HCl are combined and react to completion. How many liters of hydrogen gas, measured at STP, are produced? Mg(s) + 2HCl(aq) \rightarrow MgCl2(aq) + H2(g)


A) 2.24 L of H2
B) 4.48 L of H2
C) 5.60 L of H2
D) 11.2 L of H2
E) 22.4 L of H2

F) A) and B)
G) C) and E)

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A sample of an ideal gas has its volume doubled while its temperature remains constant. If the original pressure was 100 torr, what is the new pressure?


A) 10 torr
B) 50 torr
C) 100 torr
D) 200 torr
E) 1000 torr

F) A) and D)
G) A) and E)

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The volume of a single molecule of water is 2.99 *10¯23 mL. For a sample of gaseous water at 1.00 atm and 150 °\degree C, what fraction of the container's volume is occupied by the molecules themselves?


A) 5.2 * 10¯7
B) 4.5 *10¯5
C) 5.2 * 10¯4
D) 5.2 * 10¯1
E) None of these choices is correct.

F) A) and B)
G) A) and C)

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What is the density of carbon dioxide gas at -25.2 °\degree C and 98.0 kPa?


A) 0.232 g/L
B) 0.279 g/L
C) 0.994 g/L
D) 1.74 g/L
E) 2.09 g/L

F) B) and D)
G) C) and D)

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